EN10025-4 S420ML Steel

EN10025-4 S420ML Steel

S420ML Steel: EN 10025-4 Thermo-Mechanically Rolled Weldable Fine-Grain Structural Steel

Detailed material data for S420ML according to EN 10025-4: chemical composition, mechanical properties, thermal and electrical properties, equivalent grades, applications.

Thermo-mechanical rolling, cold forming, welding, machining

EN10025-4 S420ML Steel Introduction

S420ML is a thermo-mechanically rolled weldable fine-grain structural steel grade specified in EN 10025-4. The designation 'S' stands for structural steel, '420' indicates the minimum yield strength of 420 MPa for thicknesses ≤16 mm, 'M' denotes thermo-mechanical rolling (TMCP), and 'L' specifies impact toughness at a test temperature of -50 °C with a minimum energy of 27 J. This steel offers an excellent combination of high strength, good weldability, and superior low-temperature toughness. Its fine grain size is achieved through controlled rolling and cooling, eliminating the need for subsequent normalizing heat treatment. Typical applications include heavily loaded welded structures in bridge building, crane construction, offshore engineering, and heavy machinery, where weight savings combined with high safety standards are crucial. The material is supplied in the as-rolled condition (TMCP) and complies with strict limits on carbon equivalent (CEV) to ensure weldability without preheating under appropriate conditions.

EN10025-4 S420ML Steel Chemical Composition

The chemical composition of S420ML is defined by EN 10025-4. The steel is fully killed and fine-grain treated, with minimum aluminium or other grain-refining elements. The maximum carbon equivalent (CEV) values depend on the product thickness and are specified to guarantee weldability. The table lists the maximum limits unless a range or minimum is indicated.

ElementValue (max, %)Notes
Carbon (C)0.16CEV limits apply additionally
Silicon (Si)0.50-
Manganese (Mn)1.70-
Phosphorus (P)0.025-
Sulfur (S)0.020-
Nitrogen (N)0.015Total Al/N ratio ensures minimum Al content for fine-grain practice
Aluminium (Al)≥0.015 (total)Minimum total aluminium required; alternatively other grain-refining elements may be used
Niobium (Nb)0.05-
Vanadium (V)0.12-
Titanium (Ti)0.05-
Molybdenum (Mo)0.20-
Nickel (Ni)0.30-
Chromium (Cr)0.30-
Copper (Cu)0.55-
Carbon equivalent (CEV)Formula-basedCEV = C + Mn/6 + (Cr+Mo+V)/5 + (Ni+Cu)/15. Maximum CEV values depend on thickness: e.g., ≤0.39% for ≤63 mm, ≤0.41% for >63≤100 mm, etc.

EN10025-4 S420ML Steel Thermal and Electrical Physical Properties

The following physical properties are typical for low-alloy structural steels of this grade. They are not mandatory requirements of EN 10025-4 but are provided as engineering reference. Density, thermal expansion, thermal conductivity, specific heat capacity, and electrical resistivity are measured at room temperature unless otherwise noted.

PropertyValueUnitTest Condition
Density (ρ)7.85g/cm³At 20 °C
Modulus of elasticity (E)210GPaAt 20 °C
Shear modulus (G)≈81GPaAt 20 °C
Poisson's ratio (ν)0.3-At 20 °C
Thermal expansion coefficient (α)12.0 × 10⁻⁶K⁻¹From 20 °C to 100 °C
Thermal expansion coefficient (α)12.8 × 10⁻⁶K⁻¹From 20 °C to 200 °C
Thermal expansion coefficient (α)13.5 × 10⁻⁶K⁻¹From 20 °C to 400 °C
Thermal conductivity (λ)53W/(m·K)At 20 °C
Thermal conductivity (λ)50W/(m·K)At 200 °C
Specific heat capacity (cₚ)460J/(kg·K)At 20 °C
Specific heat capacity (cₚ)500J/(kg·K)At 200 °C
Electrical resistivity (ρₑ)0.22 × 10⁻⁶Ω·mAt 20 °C, typical for low-alloy steel

EN10025-4 S420ML Steel Mechanical Properties

The mechanical properties of S420ML are guaranteed for transverse test pieces (unless otherwise agreed). The minimum yield strength, tensile strength, and elongation are thickness-dependent. Impact toughness is verified at -50 °C (designation L). Bending tests are mandatory with specified mandrel diameters depending on thickness. All test results must comply with the values given in EN 10025-4.

PropertyValueUnitTest Condition / Remarks
Yield strength (ReH)≥420MPaNominal thickness ≤16 mm
Yield strength (ReH)≥400MPaNominal thickness >16 mm ≤40 mm
Yield strength (ReH)≥390MPaNominal thickness >40 mm ≤63 mm
Yield strength (ReH)≥370MPaNominal thickness >63 mm ≤80 mm
Yield strength (ReH)≥360MPaNominal thickness >80 mm ≤100 mm
Yield strength (ReH)≥340MPaNominal thickness >100 mm ≤120 mm
Tensile strength (Rm)520 – 680MPaNominal thickness ≤40 mm
Tensile strength (Rm)500 – 660MPaNominal thickness >40 mm ≤100 mm
Tensile strength (Rm)480 – 640MPaNominal thickness >100 mm ≤120 mm
Elongation after fracture (A)≥19%Gauge length L₀=5.65√S₀ (L₀=80 mm for thickness >3 mm); transverse, thickness ≤40 mm
Elongation after fracture (A)≥18%Transverse, thickness >40 mm ≤63 mm
Elongation after fracture (A)≥17%Transverse, thickness >63 mm ≤100 mm
Elongation after fracture (A)≥17%Transverse, thickness >100 mm ≤120 mm
Impact energy (KV)≥27JLongitudinal or transverse, -50 °C, 10×10 mm specimen
Bending test (mandrel diameter)2t (t ≤16 mm)-Bend angle 180°; t = specimen thickness
Bending test (mandrel diameter)3t (16 < t ≤40 mm)-Bend angle 180°
Bending test (mandrel diameter)3.5t (40 < t ≤63 mm)-Bend angle 180°
Bending test (mandrel diameter)4t (63 < t ≤100 mm)-Bend angle 180°
Bending test (mandrel diameter)5t (100 < t ≤120 mm)-Bend angle 180°

EN10025-4 S420ML Steel Fully Equivalent Material Standards and Substitute Grades

Country/RegionStandardGradeNotes
European UnionEN 10025-4S420MLOriginal grade; M = TMCP, L = -50 °C impact
InternationalISO 24314S420MLStructurally identical; adopts the same designation
GermanyDIN EN 10025-4S420MLNational adoption of EN standard
FranceNF EN 10025-4S420MLNational adoption of EN standard
United KingdomBS EN 10025-4S420MLNational adoption of EN standard
ItalyUNI EN 10025-4S420MLNational adoption of EN standard
SpainUNE EN 10025-4S420MLNational adoption of EN standard
SwedenSS-EN 10025-4S420MLNational adoption of EN standard
PolandPN-EN 10025-4S420MLNational adoption of EN standard
JapanJIS G 3106SM490B? (not fully equivalent)SM490B has yield 325 MPa, only similar if considering S420ML. No direct TMCP equivalent with L-impact.
ChinaGB/T 19879Q420GJ? (not direct)No exact match; Q420GJ has C ≤0.20 and impact at -20 °C or -40 °C.

EN10025-4 S420ML Steel Application Introduction

S420ML is specifically designed for welded steel structures that require high strength, good toughness at low temperatures, and excellent weldability. Thanks to the thermo-mechanical rolling process, the steel achieves fine grain refinement without the need for heat treatment after rolling. This makes it cost-effective for large welded components where preheating should be minimized. The guaranteed impact energy at -50 °C ensures safe application in cold climates and offshore environments.

Product Applications: Welded bridge girders and box sections, Offshore platform legs and decks, Heavy crane booms and lifting equipment, Wind turbine towers and foundations, Heavy-duty vehicle chassis, Pressure vessels (when additional HIC/SSC requirements are met), Steel pipes for structural applications, Shipbuilding components (if certified by classification societies)

Processed into products: Plate girders, Column and beam assemblies, Crane runway beams, Boom segments for mobile cranes, Submerged arc welded main frames, Welded tubular joints, Flanges and web plates, Earthmoving bucket parts, Offshore module structural elements

Application industries: Bridge construction, Heavy machinery and crane manufacturing, Offshore and marine engineering (platforms, wind turbine foundations), Civil engineering and building construction (high-rise, stadiums), Transport and vehicle manufacturing (heavy trucks, trailers, rail cars), Mining and earthmoving equipment, Pressure vessel and boiler fabrication (if supplementary certifications apply)

EN10025-4 S420ML Steel Similar and Closely Related Material Grades

Country/RegionStandardGradeNotes
European UnionEN 10025-4S420MSame strength, M = TMCP, but impact at -20 °C instead of -50 °C
European UnionEN 10025-3S420NNormalized rolled fine-grain steel, impact at -20 °C
European UnionEN 10025-3S420NLNormalized rolled, impact at -50 °C; chemical composition and toughness differ from TMCP grade
European UnionEN 10025-4S460MLHigher strength (460 MPa yield), same TMCP delivery and -50 °C impact
European UnionEN 10025-6S420QLQuenched and tempered steel, higher carbon content, impact at -50 °C, different weldability
InternationalISO 4951-2S420M, S420MLSimilar high-strength fine-grain steels for structural use
USAASTM A572/A572MGrade 60 [415 MPa]Only strength matches, no L-class impact guarantee, different production route
USAASTM A709/A709MGrade 60Bridge steel with higher toughness zones, but not identical to TMCP S420ML
ChinaGB/T 1591Q420D, Q420ESimilar yield strength, Q420E has -40 °C impact, not quite -50 °C; non-TMCP delivery possible
JapanJIS G 3106SM520CHigher strength 520 MPa class, but not the same impact temperature combination

Notes:

  • S420ML is typically delivered with a mill test certificate according to EN 10204 Type 3.1 or 3.2 as agreed.
  • The steel can be cold formed within limits; for severe forming, hot forming or stress-relief annealing may be considered, but the TMCP condition may be affected by reheating above 580 °C.
  • Welding procedures should be qualified; low hydrogen welding consumables are recommended to avoid cold cracking. Preheating is generally not required for moderate thicknesses due to low CEV.
  • The steel is fully killed and grain-refined; additional requirements for through-thickness properties (Z-quality) can be specified per EN 10164.
  • For atmospheric corrosion resistance, grades with improved weathering properties (e.g., S420W) are available under EN 10025-5, but not covered in the -4 standard.
  • All data is based on EN 10025-4:2019 edition. Earlier editions (2004) may have slightly different limits; always verify with the actual product standard.
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